Which of the following statements is false?
Which of the following statements is false?

(i) Two different solutions of sucrose of the same molality prepared in different solvents will have the same depression in freezing point.

(ii) The osmotic pressure of a solution is given by the equation Π = CRT (where C is the molarity of the solution).

(iii) Decreasing order of osmotic pressure for 0.01 M aqueous solutions of barium chloride, potassium chloride, acetic acid and sucrose is BaCl2> KCl > CH3COOH > sucrose.

(iv) According to Raoult’s law, the vapour pressure exerted by a volatile component of a solution is directly proportional to its mole fraction in the solution.

 

Correct Answer: (i) Two different solutions of sucrose of the same molality prepared in different solvents will have the same depression in freezing point.

Explanation: The depression in freezing point depends upon the molarity of a solution and the solute present in the solution.