Which of the following binary mixtures will have the same composition in the liquid and vapour phase?
Which of the following binary mixtures will have the same composition in the liquid and vapour phase?

(i) Benzene – Toluene

(ii) Water-Nitric acid

(iii) Water-Ethanol

(iv) n-Hexane – n-Heptane

 

Correct Answers:

(ii) Water-Nitric acid

(iii) Water-Ethanol

Explanation: In a particular composition, the Water-Nitric acid and Water-Ethanol form an azeotropic mixture with similar concentrations in the vapor phase and the aqueous phase.