According to the question,
Let \[{{z}_{1}}~=\text{ }|{{z}_{1}}|\text{ }(cos\text{ }{{\theta }_{1}}~+\text{ }I\text{ }sin\text{ }{{\theta }_{1}})\text{ }and\text{ }{{z}_{2}}~=\text{ }|{{z}_{2}}|\text{ }(cos\text{ }{{\theta }_{2}}~+\text{ }I\text{ }sin\text{ }{{\theta }_{2}})\]
Given that |z1| = |z2|
And \[\begin{array}{*{35}{l}}
arg\text{ }({{z}_{1}})\text{ }+\text{ }arg\text{ }({{z}_{2}})\text{ }=\text{ }\pi \\
\Rightarrow ~{{\theta }_{1}}~+\text{ }{{\theta }_{2}}~=\text{ }\pi \\
\Rightarrow ~{{\theta }_{1}}~=\text{ }\pi-\text{ }\text{ }{{\theta }_{2}} \\
Now,\text{ }{{z}_{1}}~=\text{ }|{{z}_{2}}|\text{ }(cos\text{ }(\pi-\text{ }\text{ }{{\theta }_{2}})\text{ }+\text{ }I\text{ }sin\text{ }(\pi- \text{ }\text{ }{{\theta }_{2}})) \\
\Rightarrow ~{{z}_{1}}~=\text{ }|{{z}_{2}}|\text{ }(-cos\text{ }{{\theta }_{2}}~+\text{ }I\text{ }sin\text{ }{{\theta }_{2}}) \\
\Rightarrow ~{{z}_{1}}~=\text{ }-|{{z}_{2}}|\text{ }(cos\text{ }{{\theta }_{2}}~\text{ }I\text{ }+sin\text{ }{{\theta }_{2}}) \\
\Rightarrow ~{{z}_{1}}~=\text{ }\text{ }[|{{z}_{2}}|\text{ }(cos\text{ }{{\theta }_{2}}~\text{ }I\text{ }+sin\text{ }{{\theta }_{2}})] \\
\end{array}\]
Hence, z1 = -z̅2
Hence proved.