What do you expect the nature of hydrides is, if formed by elements of atomic numbers 15,19, 23 and 44 with dihydrogen? Compare their behaviour with water.
What do you expect the nature of hydrides is, if formed by elements of atomic numbers 15,19, 23 and 44 with dihydrogen? Compare their behaviour with water.

Solution:

The components of nuclear numbers 15 is phosphorus, 19 potassium, 23 is vanadium and 44 is ruthenium

Hydride of Phosphorus

Hydride of phosphorus $\left(\mathrm{PH}_{3}\right.$ ) is covalent in nature. Because of the presence of abundance electrons as a solitary pair on Phosphorus, it is electron rich.

Hydride of potassium

Because of high electropositive nature of potassium, the dihydrogen structures ionic hydrides alongside potassium. Normally it is non – unpredictable and translucent.

Hydrides of Vanadium

Vanadium have a place with d-block in occasional table. The metals of d-block structures non-stoichiometric or metallic hydrides. Hydrides of vanadium are normally metallic and have inadequacy of hydrogen.

Hydrides of Ruthenium

Ruthenium has a place with $d$ – block in the occasional table. The metals of $d$ – block structures non-stoichiometric or metallic hydrides. Hydrides of ruthenium are normally metallic and have lack of hydrogen.

Conduct of hydrides towards water

P otassium hydride responds viciously with water as:

$K H_{(s)}+H_{2} O_{(a q)} \rightarrow K O H_{(a q)}+H_{2(g)}$

Smelling salts $\left(\mathrm{NH}_{3}\right)$ acts as a Lewis base and responds with water as:

$H_{2} O_{(l)}+N H_{3(a q)} \rightarrow O H_{(a q)}^{-}+N H_{4(a q)}^{+}$

Hydrides of vanadium and Ruthenium don’t respond with water. Subsequently, the expanding request of reactivity of the hydrides is $(\mathrm{V}, \mathrm{Ru}) \mathrm{H}<\mathrm{PH}_{3}<\mathrm{KH}$.