India Site

Consider the reactions :Identify $A, X, Y$ and $Z$ (1) A-Methoxymethane, X-Ethanol, Y-Ethanoic acid, Z-Semicarbazide (2) A-Ethanal, X-Ethanol, Y-But-2-enal, Z-Semicarbazone (3) A-Ethanol, X-Acetaldehyde, Y-Butanone, Z-Hydrazone (4) A-Methoxymethane, X-Ethanoic acid, Y-Acetate, ion, Z-hydrazine

Answer (2)
Sol. Since ‘A’ gives positive silver mirror test therefore, it must be an aldehyde or $\alpha$-Hydroxyketone.

Reaction with semicarbazide indicates that A can be an aldehyde or ketone.

Reaction with $\mathrm{OH}^{-}$i.e., aldol condensation (by assuming alkali to be dilute) indicates that $A$ is aldehyde as aldol reaction of ketones is reversible and carried out in special apparatus.
These indicates option (2).