Column I Column II (i) Mass percentage (a)Number of moles of the solute component/ The volume of solution in litres (ii) Volume percentage (b) Number of moles of a component/...
Match the laws given in Column I with expressions given in Column II.
Column I Column II (i) Raoult’s law (a) ∆Tf= Kfm (ii) Henry’s law (b) Π = CRT (iii) Elevation of boiling point (c) p = x1P10+ X2P20 (iv) Depression in freezing point (d) ∆Tb= Kbm (v) Osmotic...
Match the items given in Column I with the type of solutions given in Column II.
Column I Column II (i) Soda water (a) A solution of the gas in solid (ii) Sugar solution (b) A solution of the gas in gas (iii) German silver (c) A solution of...
Match the items given in Column I and Column II.
Column I Column II (i) Saturated solution (a) Solution having the same osmotic pressure at a given temperature as that of the given solution. (ii) Binary solution (b) A solution whose...
Give an example of a material used for making semipermeable membrane for carrying out reverse osmosis.
Examples: Cellulose acetate Polyamides
What is a “semi-permeable membrane”?
Semi-permeable membrane is a membrane that allows only the movement of solvent molecules but not solute molecules. Examples: Cellulose acetate and phospholipid bilayer in biological cells.
How does sprinkling of salt help in clearing the snow-covered roads in hilly areas? Explain the phenomenon involved in the process.
Salt is an agent for de-icing and can be used to dissolve ice. If the freezing point is lowered the ice begins to melt. Thus, the addition of salt to ice reduces the freezing point from O ℃ drop.
Why is the vapour pressure of an aqueous solution of glucose lower than that of water?
An example of water and glucose can be taken to illustrate this. In water, the surface of this liquid will settle with water molecules. If we put glucose into it, some of these areas will be...
On the basis of information given mark the correct option. Information: On adding acetone to methanol some of the hydrogen bonds between methanol molecules break.
(i) At specific composition, methanol-acetone mixture will form minimum boiling azeotrope and will show positive deviation from Raoult’s law. (ii) At specific composition, methanol-acetone mixture...
(a) Explain the following phenomena with the help of Henry’s law. (i) A painful condition known as bends. (ii) Feeling of weakness and discomfort in breathing at high altitude. (b) Why soda water bottle kept at room temperature fizzes on opening?
(a) (i) The bend is a condition that occurs in scuba divers. They have to breathe air under high pressure under water. Nitrogen gas does not dissolve in normal pressure. Under water, they will...
Why are aquatic species more comfortable in cold water in comparison to warm water?
Because of the availability of O2 and the presence of more solubility in the cold water makes the aquatic species feel more comfortable when present in the cold water.
What is the significance of Henry’s Law constant KH?
Significance of Henry’s Law constant KH: Henry's law states that in the solution, "the pressure in the gas component at the vapor fraction (p) is equal to the fraction of the gas molecule (x) in...
Concentration terms such as mass percentage, ppm, mole fraction and molality are independent of temperature, however, molarity is a function of temperature. Explain.
Any change in the temperature causes a change in the volume, so it changes the molarity of the solution. Therefore, terms such as high percentage, ppm, mole fraction, and molality of a solution are...
Explain the solubility rule “like dissolves like” in terms of intermolecular forces that exist in solutions.
"Like dissolves like" term is used when the solvent dissolves in the solvent if its interactions between molecules are the same. This is because polar solutions can be dissolved in polar solvents...
Explain why on the addition of 1 mol of NaCl to 1 litre of water, the boiling point of water increases, while the addition of 1 mol of methyl alcohol to one litre of water decreases its boiling point.
Adding 1 mol of NaCl to 1 liter of water, a point of boiling water rises, while the addition of 1 mol of methyl alcohol to one liter of water reduces its boiling point because when added to a stable...
Components of a binary mixture of two liquids A and B were being separated by distillation. After some time separation of components stopped and the composition of the vapour phase became the same as that of a liquid phase. Both the components started coming in the distillate. Explain why this happened.
An azeotropic mixture is shown when both the liquids A & B starts coming in the distillate and the vapour and liquid phase will have the same composition. Via distillation an azeotropic mixture...
Colligative properties are observed when _____________.
(i) a non-volatile solid is dissolved in a volatile liquid. (ii) a non-volatile liquid is dissolved in another volatile liquid. (iii) a gas is dissolved in non-volatile liquid. (iv) a volatile...
For a binary ideal liquid solution, the variation in total vapour pressure versus the composition of the solution is given by which of the curves?
Correct Answers: Option (ii) Option (iv) Explanation: For the binary solution, the difference in vapor pressure versus the composition of the solution is given in graphs B and D where, the...
In isotonic solutions ________________.
(i) solute and solvent both are same. (ii) osmotic pressure is the same. (iii) solute and solvent may or may not be same. (iv) a solute is always the same solvent may be different. Correct...
Which of the following binary mixtures will have the same composition in the liquid and vapour phase?
(i) Benzene – Toluene (ii) Water-Nitric acid (iii) Water-Ethanol (iv) n-Hexane – n-Heptane Correct Answers: (ii) Water-Nitric acid (iii) Water-Ethanol Explanation: In a particular...
Isotonic solutions must have the same _____________.
(i) solute (ii) density (iii) elevation in boiling point (iv) depression in freezing point Correct Answers: (iii) elevation in boiling point (iv) depression in freezing point Explanation:...
Van’t Hoff factor is given by the expression _____________.
(i) i = Normal molar mass/Abnormal molar mass (ii) i = Abnormal molar mass/ Normal molar mass (iii) i= Observed colligative property/calculated colligative property (iv) i = Calculated colligative...
Relative lowering of vapour pressure is a colligative property because _____________.
(i) It depends on the concentration of a non-electrolyte solute in a solution and does not depend on the nature of the solute molecules. (ii) It depends on a number of particles of electrolyte...
Intermolecular forces between two benzene molecules are near to same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?
(i) ∆mix H = zero (ii) ∆mix V = zero (iii) These will form a minimum boiling azeotrope. (iv) These will not form the ideal solution. Correct Answers: (iii) These will form a minimum boiling...
Which of the following factor (s) affect the solubility of a gaseous solute in a fixed volume of liquid solvent? (a) nature of solute (b) temperature (c) pressure
(i) (a) and (c) at constant T (ii) (a) and (b) at constant P (iii) (b) and (c) only (iv) (c) only Correct Answers: (i) (a) and (c) at constant T (ii) (a) and (b) at constant P Explanation: At...
KH value for Ar(g), CO2(g), HCHO (g) and CH4(g) are 40.39, 1.67, 1.83×10–5 and 0.413 respectively. Arrange these gases in the order of their increasing solubility.
(i) HCHO < CH4< CO2 < Ar (ii) HCHO < CO2< CH4< Ar (iii) Ar < CO2< CH4< HCHO (iv) Ar < CH4 < CO2 < HCHO Correct Answer: (iii) Ar < CO2< CH4< HCHO...
4L of 0.02 M aqueous solution of NaCl was diluted by adding one litre of water. The molality of the resultant solution is _____________.
(i) 0.004 (ii) 0.008 (iii) 0.012 (iv) 0.016 Correct Answer: (iv) 0.016 Explanation: Let us take, M1 and V1 - molarity and volume of the given solution. M2 and V2 - molarity and volume of...
If two liquids A and B form minimum boiling azeotrope at some specific composition then _______________.
(i) A–B interactions are stronger than those between A–A or B–B. (ii) vapour pressure of solution increases because more number of molecules of liquids A and B can escape from the solution. (iii)...
Two beakers of capacity 500 mL were taken. One of these beakers, labeled as “A”, was filled with 400 mL water whereas the beaker labelled “B” was filled with 400 mL of 2 M solution of NaCl. At the same temperature, both the beakers were placed in closed containers of the same material and same capacity as shown in Figure. At a given temperature, which of the following statement is correct about the vapour pressure of pure water and that of NaCl solution.
(i) the vapour pressure in container (A) is more than that in a container (B). (ii) the vapour pressure in container (A) is less than that in the container (B). (iii) vapour pressure is equal in...
On the basis of information given below mark the correct option. Information:
(A) In bromoethane and chloroethane mixture intermolecular interactions of A–A and B–B type are nearly the same as A–B type interactions. (B) In ethanol and acetone mixture A–A or B–B type...
We have three aqueous solutions of NaCl labelled as ‘A’, ‘B’ and ‘C’ with concentrations 0.1M, 0.01M and 0.001M, respectively. The value of van’t Hoff factor for these solutions will be in the order______.
(i) iA< iB< iC (ii) iA> iB> iC (iii) iA= iB= iC (iv) iA<iB> iC Correct Answer: (iii) iA= iB= iC
Consider the Figure and mark the correct option.
(i) water will move from the side (A) to side (B) if a pressure lower than the osmotic pressure is applied on piston (B). (ii) water will move from the side (B) to side (A) if a pressure greater...
The value of Henry’s constant KH is _____________.
(i) greater for gases with higher solubility. (ii) greater for gases with lower solubility. (iii) constant for all gases. (iv) not related to the solubility of gases Correct Answer: (ii)...
Value of Henry’s constant KH ____________.
(i) increases with increase in temperature. (ii) decreases with increase in temperature. (iii) remains constant. (iv) first increases then decrease. Correct Answer: (i) increases with...
Which of the following statements is false?
(i) Units of atmospheric pressure and osmotic pressure are the same. (ii) In reverse osmosis, solvent molecules move through a semipermeable membrane from a region of lower concentration of solute...
The values of Van’t Hoff factors for KCl, NaCl and K2SO4, respectively, are _____________.
(i) 2, 2 and 2 (ii) 2, 2 and 3 (iii) 1, 1 and 2 (iv) 1, 1 and 1 Correct Answer: (ii) 2, 2 and 3 Explanation: The values of van't Hoff factors for KCl,...
Which of the following statements is false?
(i) Two different solutions of sucrose of the same molality prepared in different solvents will have the same depression in freezing point. (ii) The osmotic pressure of a solution is given by the...
At a given temperature, osmotic pressure of a concentrated solution of a substance _____________.
(i) is higher than that at a dilute solution. (ii) is lower than that of a dilute solution. (iii) is same as that of a dilute solution. (iv) cannot be compared with an osmotic pressure of a dilute...
An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _____________.
(i) it gains water due to osmosis. (ii) it loses water due to reverse osmosis. (iii) it gains water due to reverse osmosis. (iv) it loses water due to osmosis. Correct Answer: (iv) it loses...
In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is _____________.
(i) the same (ii) about twice (iii) about three times (iv) about six times Correct Answer: (iii) about three times Explanation: The depression in freezing point of a 0.01M MgCl2 solution is...
The unit of ebulioscopic constant is _______________.
(i) K kg mol-1 or K (molality)-1 (ii) mol kg K-1 or K-1(molality) (iii) kg mol-1 K-1 or K-1(molality)-1 (iv) K mol kg-1 or K (molality) Correct Answer: (i) K kg mol-1 or K (molality)-1...
Which of the following aqueous solutions should have the highest boiling point?
(i) 1.0 M NaOH (ii) 1.0 M Na2SO4 (iii) 1.0 M NH4NO3 (iv) 1.0 M KNO3 Correct Answer: (ii) 1.0 M Na2SO4 Explanation: Given that a large amount of van's Hoff will increase the boiling point of...
Colligative properties depend on ____________.
(i) the nature of the solute particles dissolved in solution. (ii) the number of solute particles in solution. (iii) the physical properties of the solute particles dissolved in solution. (iv) the...
Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
(i) Methanol and acetone. (ii) Chloroform and acetone. (iii) Nitric acid and water. (iv) Phenol and aniline. Correct Answer: (i) Methanol and acetone Explanation: The mixture of methanol and...
Low concentration of oxygen in the blood and tissues of people living at high altitude is due to ____________.
(i) low temperature (ii) low atmospheric pressure (iii) high atmospheric pressure (iv) both low temperature and high atmospheric pressure Correct Answer: (ii) low atmospheric pressure...
The maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon ____________.
(i) Temperature (ii) Nature of solute (iii) Pressure (iv) Nature of solvent Correct Answer: (iii) Pressure Explanation: Changes in pressure do not affect the solubility of solids and the...
A beaker contains a solution of a substance ‘A’. Precipitation of substance ‘A’ takes place when a small amount of ‘A’ is added to the solution. The solution is _________.
(i) saturated (ii) supersaturated (iii) unsaturated (iv) concentrated Correct Answer: (ii) supersaturated Explanation: Most of the substance does not dissolve when we add more solute will not...
At equilibrium the rate of dissolution of a solid solute in a volatile liquid solvent is __________.
(i) less than the rate of crystallisation (ii) greater than the rate of crystallisation (iii) equal to the rate of crystallisation (iv) zero Correct Answer: (iii) equal to the rate of...
On dissolving sugar in water at room temperature solution feels cool to touch. Under which of the following cases dissolution of sugar will be most rapid?
(i) Sugar crystals in cold water. (ii) Sugar crystals in hot water. (iii) Powdered sugar in cold water. (iv) Powdered sugar in hot water. Correct Answer: (iv) Powdered sugar in hot water...
Which of the following units is useful in relating the concentration of a solution with its vapour pressure?
(i) mole fraction (ii) parts per million (iii) mass percentage (iv) molality Correct Answer: (i) mole fraction Explanation: According to Raoult's law, the reduction associated with vapor...